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Cerium (Ce)

Cerium is the 58th element, a lanthanide in the f-block. Its standard atomic weight is 140.116.

Period 6f-blockLanthanide
58Ce

Cerium

140.116

What the table records

Atomic number
58
Standard atomic weight
140.116
Group
Not assigned — see below
Period
6
Block
f-block
Category
Lanthanide
Electron configuration
[Xe] 4f1 5d1 6s2
Valence electrons
4
Typical valence
Variable — no single default
Van der Waals radius
2.48 Å
Covalent radius
2.04 Å

The configuration above is the documented ground state (departs from the aufbau order). Elements in the f-block are given no group number here, because which of lanthanum and lutetium belongs in group 3 is unsettled.

How to read these numbers

The standard atomic weight is an average over the isotopes as they occur naturally, which is why it is rarely a whole number. It is the figure a molar mass calculation uses. Work in mass spectrometry wants the monoisotopic mass of a single isotope instead, which is a different number.

The two radii are not the same measurement. The covalent radius is half the distance between two bonded atoms of the element; the van der Waals radius is how close a non-bonded atom gets before repulsion takes over, and is always the larger. Space-filling models are drawn with the second, ball-and-stick models with the first — which is why the same molecule looks so different in the two.