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Lithium (Li)

Lithium is the 3rd element, a alkali metal in the s-block. Its standard atomic weight is 6.941.

Period 2Group 1s-blockAlkali metal
3Li

Lithium

6.941

What the table records

Atomic number
3
Standard atomic weight
6.941
Group
1
Period
2
Block
s-block
Category
Alkali metal
Electron configuration
[He] 2s1
Valence electrons
1
Typical valence
1
Van der Waals radius
2.2 Å
Covalent radius
1.28 Å

The configuration above is the aufbau order.

How to read these numbers

The standard atomic weight is an average over the isotopes as they occur naturally, which is why it is rarely a whole number. It is the figure a molar mass calculation uses. Work in mass spectrometry wants the monoisotopic mass of a single isotope instead, which is a different number.

The two radii are not the same measurement. The covalent radius is half the distance between two bonded atoms of the element; the van der Waals radius is how close a non-bonded atom gets before repulsion takes over, and is always the larger. Space-filling models are drawn with the second, ball-and-stick models with the first — which is why the same molecule looks so different in the two.