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Vanadium (V)

Vanadium is the 23rd element, a transition metal in the d-block. Its standard atomic weight is 50.944.

Period 4Group 5d-blockTransition metal
23V

Vanadium

50.944

What the table records

Atomic number
23
Standard atomic weight
50.944
Group
5
Period
4
Block
d-block
Category
Transition metal
Electron configuration
[Ar] 3d3 4s2
Valence electrons
5
Typical valence
Variable — no single default
Van der Waals radius
2.05 Å
Covalent radius
1.52 Å

The configuration above is the aufbau order.

Molecules containing vanadium

No named structure here contains V yet.

How to read these numbers

The standard atomic weight is an average over the isotopes as they occur naturally, which is why it is rarely a whole number. It is the figure a molar mass calculation uses. Work in mass spectrometry wants the monoisotopic mass of a single isotope instead, which is a different number.

The two radii are not the same measurement. The covalent radius is half the distance between two bonded atoms of the element; the van der Waals radius is how close a non-bonded atom gets before repulsion takes over, and is always the larger. Space-filling models are drawn with the second, ball-and-stick models with the first — which is why the same molecule looks so different in the two.