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Dichlorofluoromethane

CHCl2F, 102.923 g/mol. Its structure, the values that were measured, the values that were calculated, and where each one came from.

Organic — organohalide8 measured properties

Drawn from the SMILES. It shows how the atoms are connected — not a photograph of a molecule, and not its shape in space.

Identifiers

Molecular formula
CHCl₂F
Molecular weight
102.923 g/mol
Exact mass
101.943934 g/mol
SMILES
FC(Cl)Cl
InChI
InChI=1S/CHCl2F/c2-1(3)4/h1H
InChIKey
UMNKXPULIDJLSU-UHFFFAOYSA-N

Both are open without an account.

Measured properties

Values somebody obtained from a sample and published. Where two sources report the same property they are both shown, in the units each used — a disagreement between them is information, and averaging it away would be inventing a number neither one gave.

Boiling Point
48 °F at 760 mmHg (USCG, 1999)measured · U.S. Coast Guard. 1999. Chemical Hazard Response Information System (CHRIS) - Hazardous Chemical Data. Commandant Instruction 16465.12C. Washington, D.C.: U.S. Government Printing Office.
8.9 °Cmeasured · Haynes, W.M. (ed.). CRC Handbook of Chemistry and Physics. 95th Edition. CRC Press LLC, Boca Raton: FL 2014-2015, p. 3-162
Heat of vaporization = 5.79 Kcal/mol at 25 °C; 6.01 kcal/mol at the boiling pointmeasured · Riddick, J.A., W.B. Bunger, Sakano T.K. Techniques of Chemistry 4th ed., Volume II. Organic Solvents. New York, NY: John Wiley and Sons., 1985., p. 560
8.9 °Cmeasured · reference compound database
48 °Fmeasured · reference compound database
8.9 °C @760 [mm Hg]measured · reference compound database
48 °Fmeasured · reference compound database
Melting Point
-211 °F (USCG, 1999)measured · U.S. Coast Guard. 1999. Chemical Hazard Response Information System (CHRIS) - Hazardous Chemical Data. Commandant Instruction 16465.12C. Washington, D.C.: U.S. Government Printing Office.
-130.4 °Cmeasured · Haynes, W.M. (ed.). CRC Handbook of Chemistry and Physics. 95th Edition. CRC Press LLC, Boca Raton: FL 2014-2015, p. 3-162
-135 °Cmeasured · reference compound database
-211 °Fmeasured · reference compound database
-130.4 °Cmeasured · reference compound database
-211 °Fmeasured · reference compound database
Solubility
0.7 % at 86 °F (NIOSH, 2024)measured · reference compound database
In water, 1.88X10+04 mg/L at 25 °Cmeasured · Horvath AL; Halogenated Hydrocarbons. NY, NY: Marcel Dekker, Inc. p. 649 (1982)
Soluble in carbon tetrachloridemeasured · Haynes, W.M. (ed.). CRC Handbook of Chemistry and Physics. 95th Edition. CRC Press LLC, Boca Raton: FL 2014-2015, p. 3-162
69 parts/100 parts acetic acid; 108 parts/100 parts dioxanemeasured · Dean, J.A. Handbook of Organic Chemistry. New York, NY: McGraw-Hill Book Co., 1987., p. 1-182
> 10% in ethyl alcohol; > 10% in ethyl ether;> 10% in chloroformmeasured · Weast, R.C. and M.J. Astle. CRC Handbook of Data on Organic Compounds. Volumes I and II. Boca Raton, FL: CRC Press Inc. 1985., p. V1 840
0.95% weight at 25 deg in watermeasured · Riddick, J.A., W.B. Bunger, Sakano T.K. Techniques of Chemistry 4th ed., Volume II. Organic Solvents. New York, NY: John Wiley and Sons., 1985., p. 561
Solubility in water, g/100ml at 20 °C: 1 (poor)measured · reference compound database
(86 °F): 0.7%measured · reference compound database
Density
1.48 at 68 °F (USCG, 1999) - Denser than water; will sinkmeasured · U.S. Coast Guard. 1999. Chemical Hazard Response Information System (CHRIS) - Hazardous Chemical Data. Commandant Instruction 16465.12C. Washington, D.C.: U.S. Government Printing Office.
Density: 1.405 g/cu cm 9 °Cmeasured · Haynes, W.M. (ed.). CRC Handbook of Chemistry and Physics. 95th Edition. CRC Press LLC, Boca Raton: FL 2014-2015, p. 3-162
1.48measured · reference compound database
1.405 @ 9°Cmeasured · reference compound database
3.57(relative gas density)measured · reference compound database
Vapor Pressure
2217.93 mmHg (USCG, 1999)measured · U.S. Coast Guard. 1999. Chemical Hazard Response Information System (CHRIS) - Hazardous Chemical Data. Commandant Instruction 16465.12C. Washington, D.C.: U.S. Government Printing Office.
1360 mm Hg at 25 °Cmeasured · Daubert, T.E., R.P. Danner. Physical and Thermodynamic Properties of Pure Chemicals Data Compilation. Washington, D.C.: Taylor and Francis, 1989.
Vapor pressure, kPa at 21 °C: 159measured · reference compound database
1.6 atm at 70 °Fmeasured · reference compound database
750 [mm Hg] @8.6 °Cmeasured · reference compound database
(70 °F): 1.6 atmmeasured · reference compound database
LogP
log Kow = 1.55measured · Hansch, C., Leo, A., D. Hoekman. Exploring QSAR - Hydrophobic, Electronic, and Steric Constants. Washington, DC: American Chemical Society., 1995., p. 3
1.55measured · reference compound database
1.55measured · reference compound database
Viscosity
0.313 cP at 25 °C (liq); 0.0114 cP at 25 °C, 101.3 kPa ... /gas/measured · Kirk-Othmer Encyclopedia of Chemical Technology. 3rd ed., Volumes 1-26. New York, NY: John Wiley and Sons, 1978-1984., p. V10: 862
Refractive Index
Index of refraction: 1.3724 @ 9 °C/Dmeasured · Haynes, W.M. (ed.). CRC Handbook of Chemistry and Physics. 95th Edition. CRC Press LLC, Boca Raton: FL 2014-2015, p. 3-162

Calculated properties

Derived from the structure rather than from a sample. These are reproducible and they are not measurements: a calculated partition coefficient and a measured one can differ by a long way, and where both exist they are listed apart on purpose.

logP
1.7171calculated · chemistry engine
Estimated preference for oil over water. Higher means more oil-like.
Topological polar surface area
0 Ųcalculated · chemistry engine
Surface area from polar atoms; relates to how easily a molecule crosses membranes.
H-bond donors
0calculated · chemistry engine
Atoms that can donate a hydrogen bond.
H-bond acceptors
0calculated · chemistry engine
Atoms that can accept a hydrogen bond.
Rotatable bonds
0calculated · chemistry engine
Single bonds the molecule can freely twist around.
Molar refractivity
16.602 cm³/molcalculated · chemistry engine
Relates to the molecule's polarisability.
Fraction sp³ carbons
1calculated · chemistry engine
Share of carbon atoms with tetrahedral bonding.
QED drug-likeness
0.4091calculated · chemistry engine
Quantitative estimate of drug-likeness (0–1).

What it is made of

Elements

Percentages are of the molecular weight above, worked out the same way the molar mass calculator does it.

Structure

Heavy atoms, hydrogen excluded
4
Total atoms, hydrogen included
5
Rings
0
Aromatic rings
0
Stereocentres
0
Formal charge
0

Functional groups

  • Halide (C–X)

    A halogen atom attached to carbon.

Matched by structural pattern, not by a measurement.

The molecule in three dimensions

Rotate and inspect the atoms. Loaded only when you ask, so the page stays light.

The drawing above is a diagram of what is bonded to what. A molecule is not flat, and the model here is one low-energy shape generated from the connectivity — useful for seeing which groups can reach each other, and not a measured structure. A real sample is a population of conformations, interconverting.

Reactions it appears in

No documented reaction with a written procedure and a source involves Dichlorofluoromethane yet.

Other names for it

No systematic name is recorded.

The sources also call it Fluorodichloromethane, Dichloromonofluoromethane, Algofrene type 5, Arcton 7, Genetron 21, Monofluorodichloromethane, Refrigerant 21, HCFC-21, Methane, dichlorofluoro-, Fluorocarbon 21, FREON 21, Freon F 21.

Structurally related

Nothing structurally close to Dichlorofluoromethane has a page here yet.

Where these values came from

  • chemistry engine

    structure perception

No matching record was found in the currently indexed sources (reference compound database)..

What this page does not claim

The identifiers are what the source record holds, copied rather than recomputed. Measured values are reported as their source gave them, units and all; calculated values are marked as calculated and are not measurements. Where a field is absent the page says so, because a blank cell reads as a zero and a guessed value reads as a fact.

Nothing here is a hazard assessment, a purity statement or advice about handling a sample. A flash point quoted from a safety database is a number somebody published, not a judgement by us about whether this molecule is safe for what you intend.