Ethyl chloroformate

An ester, C3H5ClO2, 108.524 g/mol. Boiling point 95 °C @ 760 MM HG, melting point -80.6 °C, as published.

verified recordOrganic — ester7 measured properties

Identifiers

Molecular formula: C₃H₅ClO₂
Molecular weight: 108.524 g/mol
Exact mass: 107.997807 g/mol
IUPAC name: ethyl carbonochloridate
SMILES: CCOC(=O)Cl
InChI: InChI=1S/C3H5ClO2/c1-2-6-3(4)5/h2H2,1H3
InChIKey: RIFGWPKJUGCATF-UHFFFAOYSA-N

Open in ReactionLens Use in reaction prediction

Measured properties

Published measurements, each with its source. Two readings of one property are both shown, in the units each used.

Boiling Point: 201 °F at 760 mmHg (USCG, 1999)measured · CAMEO Chemicals; 95 °C @ 760 MM HGmeasured · Hazardous Substances Data Bank (HSDB)
Melting Point: -114 °F (USCG, 1999)measured · CAMEO Chemicals; -80.6 °Cmeasured · Hazardous Substances Data Bank (HSDB)
Density: 1.135 at 68 °F (USCG, 1999) - Denser than water; will sinkmeasured · CAMEO Chemicals; 1.1403 @ 20 °C/4 °Cmeasured · Hazardous Substances Data Bank (HSDB)
Solubility: PRACTICALLY INSOL & GRADUALLY DECOMP IN WATERmeasured · Hazardous Substances Data Bank (HSDB); MISCIBLE WITH ALC, BENZENE, CHLOROFORM, ETHERmeasured · Hazardous Substances Data Bank (HSDB)
Vapor Pressure: 22.4 [mmHg]measured · Haz-Map, Information on Hazardous Chemicals and Occupational Diseases; 22.4 mm Hg @ 25 °Cmeasured · Hazardous Substances Data Bank (HSDB)
Flash Point: 61 °F (USCG, 1999)measured · CAMEO Chemicals; 16 °Cmeasured · Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
Refractive Index: INDEX OF REFRACTION: 1.3947 @ 20 °C/Dmeasured · Budavari, S. (ed.). The Merck Index - Encyclopedia of Chemicals, Drugs and Biologicals. Rahway, NJ: Merck and Co., Inc., 1989., p. 597

Calculated properties

Derived from the structure, not from a sample; kept apart from the measurements above.

Molecular weight: 108.52 g/molcalculated · reference compound database; Average mass of one molecule, from reference compound database.
Exact mass: 107.9978071 Dacalculated · reference compound database; Mass of the most common isotopic form.
XLogP3: 1.5calculated · reference compound database; Estimated oil/water partition, computed by reference compound database.
Polar surface area: 26.3 Å²calculated · reference compound database; Polar surface area as computed by reference compound database.
Complexity: 52calculated · reference compound database; A rough measure of how intricate the structure is.
H-bond donors: 0calculated · reference compound database
H-bond acceptors: 2calculated · reference compound database
logP: 1.3817calculated · chemistry engine; Estimated preference for oil over water. Higher means more oil-like.
Topological polar surface area: 26.3 Å²calculated · chemistry engine; Surface area from polar atoms; relates to how easily a molecule crosses membranes.
H-bond donors: 0calculated · chemistry engine; Atoms that can donate a hydrogen bond.
H-bond acceptors: 2calculated · chemistry engine; Atoms that can accept a hydrogen bond.
Rotatable bonds: 1calculated · chemistry engine; Single bonds the molecule can freely twist around.
Molar refractivity: 22.875 cm³/molcalculated · chemistry engine; Relates to the molecule's polarisability.
Fraction sp³ carbons: 0.6667calculated · chemistry engine; Share of carbon atoms with tetrahedral bonding.
QED drug-likeness: 0.4746calculated · chemistry engine; Quantitative estimate of drug-likeness (0–1).

What it is made of

Elements

C Carbon3 atoms · 33.2% by mass
Cl Chlorine1 atom · 32.7% by mass
O Oxygen2 atoms · 29.5% by mass
H Hydrogen5 atoms · 4.6% by mass

Percentages are of the molecular weight above, worked out the same way the molar mass calculator does it.

Structure

Heavy atoms, hydrogen excluded: 6
Total atoms, hydrogen included: 11
Rings: 0
Aromatic rings: 0
Stereocentres: 0
Formal charge: 0

Functional groups

Ester
A carbonyl bonded to an oxygen that links to another carbon.
Ether
An oxygen bridging two carbons.
Halide (C–X)
A halogen atom attached to carbon.

Matched by structural pattern, not by a measurement.

The molecule in three dimensions

Rotate and inspect the atoms. Loaded only when you ask, so the page stays light.

The drawing above is a diagram of what is bonded to what. A molecule is not flat, and the model here is one low-energy shape generated from the connectivity — useful for seeing which groups can reach each other, and not a measured structure. A real sample is a population of conformations, interconverting.

Reactions it appears in

No documented reaction with a written procedure and a source involves Ethyl chloroformate yet.

Other names for it

The systematic name on this record is ethyl carbonochloridate.

The sources also call it Ethyl carbonochloridate, Ethyl chlorocarbonate, Cathyl chloride, Ethoxycarbonyl chloride, Chloroformic acid ethyl ester, Carbonochloridic acid, ethyl ester, Chlorocarbonic acid ethyl ester, Etil cloroformiato, Ethylchloorformiaat, ETHYLCHLOROFORMATE, Etil clorocarbonato.

Structurally related

Nothing structurally close to Ethyl chloroformate has a page here yet.

Seen alongside it in reaction records

Molecules that appear in the same recorded reactions as Ethyl chloroformate. This says nothing about structure: most of them are the bases, solvents, ligands and catalysts the chemistry needed, and they are here because somebody put them in the same flask.

1,4-Dioxane

used as a reactant

C₄H₈O₂, 88.106 g/mol.

1,3,4-Thiadiazol-2-amine

used as a reactant

C₂H₃N₃S, 101.134 g/mol.

Where these values came from

reference compound database10928
compound record
chemistry engine
structure perception

compound record.

What this page does not claim

Identifiers are copied from the source record, measured values are reported as published, and calculated values are marked as calculated. Nothing here is a hazard, purity or handling assessment — how the library is checked.