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Methyl Chloride

CH3Cl, 50.488 g/mol. Its structure, the values that were measured, the values that were calculated, and where each one came from.

verified recordOrganic — organohalide9 measured properties

Drawn from the SMILES. It shows how the atoms are connected — not a photograph of a molecule, and not its shape in space.

Identifiers

Molecular formula
CH₃Cl
Molecular weight
50.488 g/mol
Exact mass
49.992328 g/mol
IUPAC name
chloromethane
SMILES
CCl
InChI
InChI=1S/CH3Cl/c1-2/h1H3
InChIKey
NEHMKBQYUWJMIP-UHFFFAOYSA-N

Both are open without an account.

Measured properties

Values somebody obtained from a sample and published. Where two sources report the same property they are both shown, in the units each used — a disagreement between them is information, and averaging it away would be inventing a number neither one gave.

Boiling Point
-11.6 °F at 760 mmHg (NTP, 1992)measured · CAMEO Chemicals
-23.7 °Cmeasured · Hazardous Substances Data Bank (HSDB)
Melting Point
-143 °F (NTP, 1992)measured · CAMEO Chemicals
-97.6 °Cmeasured · Hazardous Substances Data Bank (HSDB)
Density
0.997 at -11.2 °F (USCG, 1999) - Less dense than water; will floatmeasured · CAMEO Chemicals
0.911 g/cu cm at 25 °C (pressure > 1 atm)measured · Hazardous Substances Data Bank (HSDB)
Solubility
Slightly soluble (NTP, 1992)measured · CAMEO Chemicals
In water, 5040 mg/L at 25 °Cmeasured · Hazardous Substances Data Bank (HSDB)
Vapor Pressure
760 mmHg at -11 °F ; 3672 mmHg at 68 °F (NTP, 1992)measured · CAMEO Chemicals
4300 mm Hg at 25 °Cmeasured · Hazardous Substances Data Bank (HSDB)
LogP
log Kow = 0.91measured · Hazardous Substances Data Bank (HSDB)
0.91measured · ILO-WHO International Chemical Safety Cards (ICSCs)
Flash Point
-49.9 °F (NTP, 1992)measured · CAMEO Chemicals
-45.6 °Cmeasured · Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
Viscosity
0.00027 Pa.s at 20 °C (liquid, 0.5 MPa)measured · Rossberg M et al; Chloromethanes. Ullmann's Encyclopedia of Industrial Chemistry. 7th ed. (1999-2015). New York, NY: John Wiley & Sons. Online Posting Date: Oct 15, 2011.
0.1834 cP at 20 °Cmeasured · reference compound database
Refractive Index
Index of refraction: 1.3712 at -23.7 °C (liquid)measured · O'Neil, M.J. (ed.). The Merck Index - An Encyclopedia of Chemicals, Drugs, and Biologicals. Cambridge, UK: Royal Society of Chemistry, 2013., p. 1120

Calculated properties

Derived from the structure rather than from a sample. These are reproducible and they are not measurements: a calculated partition coefficient and a measured one can differ by a long way, and where both exist they are listed apart on purpose.

Molecular weight
50.49 g/molcalculated · reference compound database
Average mass of one molecule, from reference compound database.
Exact mass
49.9923278 Dacalculated · reference compound database
Mass of the most common isotopic form.
XLogP3
0.8calculated · reference compound database
Estimated oil/water partition, computed by reference compound database.
Polar surface area
0 Ųcalculated · reference compound database
Polar surface area as computed by reference compound database.
Complexity
2calculated · reference compound database
A rough measure of how intricate the structure is.
H-bond donors
0calculated · reference compound database
H-bond acceptors
0calculated · reference compound database
logP
0.855calculated · chemistry engine
Estimated preference for oil over water. Higher means more oil-like.
Topological polar surface area
0 Ųcalculated · chemistry engine
Surface area from polar atoms; relates to how easily a molecule crosses membranes.
H-bond donors
0calculated · chemistry engine
Atoms that can donate a hydrogen bond.
H-bond acceptors
0calculated · chemistry engine
Atoms that can accept a hydrogen bond.
Rotatable bonds
0calculated · chemistry engine
Single bonds the molecule can freely twist around.
Molar refractivity
11.777 cm³/molcalculated · chemistry engine
Relates to the molecule's polarisability.
Fraction sp³ carbons
1calculated · chemistry engine
Share of carbon atoms with tetrahedral bonding.
QED drug-likeness
0.3574calculated · chemistry engine
Quantitative estimate of drug-likeness (0–1).

What it is made of

Elements

Percentages are of the molecular weight above, worked out the same way the molar mass calculator does it.

Structure

Heavy atoms, hydrogen excluded
2
Total atoms, hydrogen included
5
Rings
0
Aromatic rings
0
Stereocentres
0
Formal charge
0

Functional groups

  • Halide (C–X)

    A halogen atom attached to carbon.

Matched by structural pattern, not by a measurement.

The molecule in three dimensions

Rotate and inspect the atoms. Loaded only when you ask, so the page stays light.

The drawing above is a diagram of what is bonded to what. A molecule is not flat, and the model here is one low-energy shape generated from the connectivity — useful for seeing which groups can reach each other, and not a measured structure. A real sample is a population of conformations, interconverting.

Reactions it appears in

No documented reaction with a written procedure and a source involves Methyl Chloride yet.

Other names for it

The systematic name on this record is chloromethane.

The sources also call it Chloromethane, Monochloromethane, Methane, chloro-, Methylchloride, Artic, CH3Cl, Methylchlorid, Clorometano, Chloor-methaan, Metylu chlorek, Chlor-methan.

Structurally related

Molecules sharing this formula, or whose fingerprint is at least 40% similar to this one. Similarity is Tanimoto on Morgan fingerprints over this library only — it is a measure of structural overlap, not of how alike they behave.

Where these values came from

compound record.

What this page does not claim

The identifiers are what the source record holds, copied rather than recomputed. Measured values are reported as their source gave them, units and all; calculated values are marked as calculated and are not measurements. Where a field is absent the page says so, because a blank cell reads as a zero and a guessed value reads as a fact.

Nothing here is a hazard assessment, a purity statement or advice about handling a sample. A flash point quoted from a safety database is a number somebody published, not a judgement by us about whether this molecule is safe for what you intend.