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Diels–Alder cycloaddition

A diene and an alkene join at both ends at once, making a six-membered ring with one double bond left in the middle.

mechanism writtenBalanced: every atom is accounted for

What it needs, and what it gives

Reaction class
Cycloaddition
Typical conditions
Heat. The alkene reacts faster when it carries an electron-withdrawing group.
Mass balance
balanced — the co-products are written out, not dropped
Mechanism
Diels-Alder cycloaddition, one concerted step

Conditions are what the literature ordinarily uses, recorded so you can see whether yours are in the usual range. They are not a procedure and they are not scaled to your flask.

How it is thought to happen

One step. Six electrons move round a ring at once, two new single bonds form at the ends and the double bond ends up in the middle.

  1. Six electrons move round at once

This is the pathway taught for the class, not a record of what was observed. On the platform it is drawn on the structures you supply, with the curly arrows on the atoms that actually move.

Try it on your own structures

Enter your reactants in the Reaction Lab. If this transformation matches what you drew, it is applied and the outcome is shown next to the records that back it — with the count of documented reactions doing the same thing on substrates like yours, rather than a confidence score.