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Bismuth (Bi)

Bismuth is the 83rd element, a post-transition metal in the p-block. Its standard atomic weight is 208.98.

Period 6Group 15p-blockPost-transition metal
83Bi

Bismuth

208.98

What the table records

Atomic number
83
Standard atomic weight
208.98
Group
15
Period
6
Block
p-block
Category
Post-transition metal
Electron configuration
[Xe] 4f14 5d10 6s2 6p3
Valence electrons
5
Typical valence
3
Van der Waals radius
2.3 Å
Covalent radius
1.48 Å

The configuration above is the aufbau order.

Molecules containing bismuth

How to read these numbers

The standard atomic weight is an average over the isotopes as they occur naturally, which is why it is rarely a whole number. It is the figure a molar mass calculation uses. Work in mass spectrometry wants the monoisotopic mass of a single isotope instead, which is a different number.

The two radii are not the same measurement. The covalent radius is half the distance between two bonded atoms of the element; the van der Waals radius is how close a non-bonded atom gets before repulsion takes over, and is always the larger. Space-filling models are drawn with the second, ball-and-stick models with the first — which is why the same molecule looks so different in the two.