Skip to the content
Browse the library

Thallium (Tl)

Thallium is the 81st element, a post-transition metal in the p-block. Its standard atomic weight is 204.383.

Period 6Group 13p-blockPost-transition metal
81Tl

Thallium

204.383

What the table records

Atomic number
81
Standard atomic weight
204.383
Group
13
Period
6
Block
p-block
Category
Post-transition metal
Electron configuration
[Xe] 4f14 5d10 6s2 6p1
Valence electrons
3
Typical valence
Variable — no single default
Van der Waals radius
2.2 Å
Covalent radius
1.45 Å

The configuration above is the aufbau order.

Molecules containing thallium

The lightest named structures in this library that contain Tl.

How to read these numbers

The standard atomic weight is an average over the isotopes as they occur naturally, which is why it is rarely a whole number. It is the figure a molar mass calculation uses. Work in mass spectrometry wants the monoisotopic mass of a single isotope instead, which is a different number.

The two radii are not the same measurement. The covalent radius is half the distance between two bonded atoms of the element; the van der Waals radius is how close a non-bonded atom gets before repulsion takes over, and is always the larger. Space-filling models are drawn with the second, ball-and-stick models with the first — which is why the same molecule looks so different in the two.